Scientists and industry experts have long speculated that carbon
nanotube transistors would one day replace their silicon predecessors. In 1998,
Delft University built the world's first carbon nanotube transistors. Carbon
nanotubes have the potential to be far smaller faster, and consume less power
than silicon transistors.
A key reason carbon nanotubes are not in computers right now is
that they are difficult to manufacture in a predictable way. Scientists have
had a difficult time controlling the manufacture of nanotubes to the correct
diameter, type and ultimately chirality -- factors that control nanotubes'
electrical and mechanical properties.
Think of chirality like this: If you took a sheet of notebook
paper and rolled it straight up into a tube, it would have a certain chirality.
If you rolled that same sheet up at an angle, it would have a different
chirality. In this example, the notebook paper represents a sheet of latticed
carbon atoms that are rolled up to create a nanotube.
A team led by Professor Chongwu Zhou of the USC Viterbi School of
Engineering and Ming Zheng of the National Institute of Standards and
Technology in Maryland solved the problem by inventing a system that
consistently produces carbon nanotubes of a predictable diameter and chirality.
Zhou worked with group members Jia Liu, Chuan Wang, Bilu Liu,
Liang Chen, as well as Zheng and Xiaomin Tu of the National Institute of
Standards and Technology.
"Controlling the chirality of carbon nanotubes has been a
dream for many researchers. Now the dream has come true," Zhou said. The
team has already patented its innovation, and its research was published Nov.
13 in Nature Communications.
Carbon nanotubes are typically grown using a chemical vapor
deposition (CVD) system in which a chemical-laced gas is pumped into a chamber
containing substrates with metal catalyst nanoparticles, upon which the
nanotubes grow. It is generally believed that the diameters of the nanotubes
are determined by the size of the catalytic metal nanoparticles. However,
attempts to control the catalysts in hopes of achieving chirality-controlled
nanotube growth have not been successful.
The USC team's innovation was to jettison the catalyst and instead
plant pieces of carbon nanotubes that have been separated and pre-selected
based on chirality, using a nanotube-separation technique developed and
perfected by Zheng and his co-workers. Using those pieces as seeds, the team
used CVD to extend the seeds to get much longer nanotubes, which were shown to
have the same chirality as the seeds.
The process is referred to as "nanotube cloning." The
next steps in the research will be to carefully study the mechanism of the
nanotube growth in this system, to scale up the cloning process to get large
quantities of chirality-controlled nanotubes and to use those nanotubes for
electronic applications.
Source:
The above story is reprinted from materials provided
by University
of Southern California. The original article was written by
Robert Perkins.
Note: Materials may be edited for content and length.
For further information, please contact the source cited above.
Journal Reference:
1. Jia Liu, Chuan Wang, Xiaomin Tu, Bilu Liu, Liang
Chen, Ming Zheng, Chongwu Zhou. Chirality-controlled synthesis of
single-wall carbon nanotubes using vapour-phase epitaxy. Nat.
Commun., 13 Nov, 2012 DOI:10.1038/ncomms2205
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